Zevenenergie,
I grinding stone should never be in contact with the workpiece along it's full circomference. That is a recipy for disaster as you found out.
In fact, I tend to think that one is better off having the seats done by a professional cylinder and head service. But if you insist on doing it by hand, even using the standard mill-type cutters, be prepared for a learning experience, and for that, a broken head is invaluable to experiment with.
As for the valves, Honda CB350 inlet valves fit well, and the standard ones are 34mm.
You can get them as 1mm oversize = 35mm diametre, here:
https://www.ebay.com/itm/174478425798I just bought another set from him.
If 35 is too much, you can grind them down to 34mm no problem.
The standard valve seat is 35mm outside, and this may lead to problems, if that is the case, I will have bigger valve seats fitted (by professionals, since they have the liquid nitrogen to shrink them into place)
Cheers, Finn Hammer